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11.
Ryosuke Sakae Dr. Koji Hirano Prof. Dr. Tetsuya Satoh Prof. Dr. Masahiro Miura 《Angewandte Chemie (International ed. in English)》2015,54(2):613-617
A copper‐catalyzed aminoboration of bicyclic alkenes, including oxa‐ and azabenzonorbornadienes, has been developed. With this method, amine and boron moieties are simultaneously introduced at an olefin with exo selectivity. Subsequent stereospecific transformations of the boryl group can provide oxygen‐ and nitrogen‐rich cyclic molecules with motifs that may be found in natural products or pharmaceutically active compounds. Moreover, a catalytic asymmetric variant of this transformation was realized by using a copper complex with a chiral bisphosphine ligand, namely (R,R)‐Ph‐BPE. 相似文献
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Tetsuya Uematsu 《Mathematische Zeitschrift》2015,279(3-4):1047-1066
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N. Kuroda S. Ulmer D. J. Murtagh S. Van Gorp Y. Nagata M. Diermaier S. Federmann M. Leali C. Malbrunot V. Mascagna O. Massiczek K. Michishio T. Mizutani A. Mohri H. Nagahama M. Ohtsuka B. Radics S. Sakurai C. Sauerzopf K. Suzuki M. Tajima H. A. Torii L. Venturelli B. Wünschek J. Zmeskal N. Zurlo H. Higaki Y. Kanai E. Lodi Rizzini Y. Nagashima Y. Matsuda E. Widmann Y. Yamazaki 《Hyperfine Interactions》2015,235(1-3):13-20
In order to test CPT symmetry between antihydrogen and its counterpart hydrogen, the ASACUSA collaboration plans to perform high precision microwave spectroscopy of ground-state hyperfine splitting of antihydrogen atom in-flight. We have developed an apparatus (“cusp trap”) which consists of a superconducting anti-Helmholtz coil and multiple ring electrodes. For the preparation of slow antiprotons and positrons, Penning-Malmberg type traps were utilized. The spectrometer line was positioned downstream of the cusp trap. At the end of the beamline, an antihydrogen beam detector was located, which comprises an inorganic Bismuth Germanium Oxide (BGO) single-crystal scintillator housed in a vacuum duct and surrounding plastic scintillators. A significant fraction of antihydrogen atoms flowing out the cusp trap were detected. 相似文献
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Katsuya Hyodo Yoshinori Arisaka Satoshi Yamaguchi Tetsuya Yoda Nobuhiko Yui 《Macromolecular bioscience》2019,19(4)
Modulation of material properties and growth factor application are critical in constructing suitable cell culture environments to induce desired cellular functions. Sulfonated polyrotaxane (PRX) surfaces with immobilized vascular endothelial growth factors (VEGFs) are prepared to improve network formation in vascular endothelial cells. Sulfonated PRXs, whereby sulfonated α‐cyclodextrins (α‐CDs) are threaded onto a linear poly(ethylene glycol) chain capped with bulky groups at both terminals, are coated onto surfaces. The molecular mobility of sulfonated PRX surfaces is modulated by tuning the number of threading α‐CDs. VEGF is immobilized onto surfaces with varying mobility. Low mobility and VEGF‐immobilization reinforce cell proliferation, yes‐associated protein activity, and rhoA, pdgf, ang‐1, and pecam‐1 gene expression. Highly mobile surfaces and soluble VEGF weakly affect these cell responses. Network formation is strongly stimulated in vascular endothelial cells only on low‐mobility VEGF‐immobilized surfaces, suggesting that molecular mobility and VEGF immobilization synergistically control cell function. 相似文献
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Toshihiro Okajima Hiroyuki Setoyama Marek Brancewicz Masahide Kawamoto Yoshiharu Sakurai 《X射线光谱测定》2020,49(3):390-397
X-ray fluorescence spectra of copper (Cu) metal, copper monoxide (CuO), and potassium chromate (K2CrO4) were recorded as a function of incident X-ray energy near the Cu K-edge and chromium (Cr) K-edge, respectively, using a conventional silicon drift detector. The spectra contained components due to elastic, inelastic, and multiple scattering, in addition to the Kα and Kβ lines. Cu and Cr K-edge X-ray absorption fine structure (XAFS) spectra of Cu, CuO, and K2CrO4 were obtained by an intensity analysis of the Kα and Kβ lines. The intensity of the Kβ line for the different incident photon energies was obtained by numerically removing the additional scattering components using the MUSCAT program. These spectra exhibited a jump near the K absorption edges, which reproduced the spectral features obtained in transmission mode for both Cu, CuO, and K2CrO4. A chemical shift was also clearly identified in the X-ray absorption near edges structure using the X-ray fluorescence Kβ line. In addition, the Cr K-edge extended XAFS spectrum of K2CrO4 was clearly observed using the Cr Kβ fluorescent line. The XAFS measurements on the Kα and Kβ lines are possible, and they carry equally valuable information. 相似文献
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Naofumi Nishida Yuki Hori Akane Yamauchi Hazuki Fujiwara Makoto Sakurai Yuya Fujiwara Shin-ichi Honda Shunjiro Fujii Hiroyuki A. Sakaue Daiji Kato Tomohiro Yamaguchi Koji Ishibashi Toshifumi Terui Kuei-Yi Lee 《X射线光谱测定》2020,49(1):99-103
Interaction of highly charged ions (HCIs) with surfaces produce various specific phenomena as a consequence of the potential energy that HCI possesses. In the present study, we have observed photon emission, structural, magnetic, and electronic modification on various carbon-based materials such as carbon nanotube by the impact of HCIs using an electron beam ion source named Kobe EBIS installed at the Kobe University. In order to study the potential effect, HCIs of Arq+ (q = 6–16) with the intensity of 0.1–1 nA are projected on the surface with a constant kinetic energy (16 keV). For photon emission measurements, we observed spatial and spectral distribution of visible light emission from the surface during irradiation with HCIs. On the other hand, the structural modification of multi-walled carbon nanotubes (MWCNTs) irradiated with HCIs has been analyzed using a transmission electron microscopy and Raman spectroscopy. Irradiation effects on the resistivity of single MWCNT supported on micrometer scale bridge pattern were also measured. We have also measured magnetic structure of highly oriented pyrolytic graphite irradiated with HCIs using electron spin resonance at low temperature. At the present paper, we will review our recent experimental results on the interaction of HCI with various carbon-based materials. 相似文献
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